US Scientists Unlock Plastic Alternatives Using Proteins and Clothing Scraps

Inspired by nature’s ability to construct a diverse array of functional materials, scientists at the University of Connecticut have developed a method to produce continuously tunable non-toxic materials.

Long Story, Cut Short
  • The team of scientists demonstrated that the protein-based material can form a variety of plastic-like products, including coffee cup lids & thin transparent films.
  • While the team has only worked with cotton so far, they expect other fibre materials, like hemp or jute, would behave similarly due to their inherent but common chemical properties with cotton.
The first innovation is a process to transform naturally occurring proteins into plastic-like materials. Proteins have “reactor groups” on their surfaces which can react with substances with which they come into contact. Using this knowledge of how these groups work, the scientists used a chemical link to bind protein molecules together.
Fabric Story The first innovation is a process to transform naturally occurring proteins into plastic-like materials. Proteins have “reactor groups” on their surfaces which can react with substances with which they come into contact. Using this knowledge of how these groups work, the scientists used a chemical link to bind protein molecules together. Prince Abid / Unsplash

A team of scientists in the US has developed two technologies that use proteins and cloth, respectively, to create new, sustainable materials. 

  • Inspired by nature’s ability to construct a diverse array of functional materials, Prof Challa Kumar and his team at the University of Connecticut have developed a method to produce continuously tunable  non-toxic materials.
  • UConn’s Technology Commercialization Services (TCS) has filed provisional patents for both technologies.

The backdrop: Kumar, professor emeritus of chemistry, “fed up” with the tremendous amount of toxic waste people continually pump into the environment, felt compelled to do something. As a chemist, doing something meant using his expertise to develop new, sustainable materials.

  • The first innovation is a process to transform naturally occurring proteins into plastic-like materials. Proteins have “reactor groups” on their surfaces which can react with substances with which they come into contact. Using this knowledge of how these groups work, the scientists used a chemical link to bind protein molecules together.
  • This process creates a dimer—a molecule composed to two proteins. From there, the dimer is joined with another dimer to create tetramer, and so on until it becomes a large 3D molecule. This 3D aspect of the technology is unique, since most synthetic polymers are linear chains.
  • This novel 3D structure allows the new polymer to behave like a plastic. Just like the proteins of which it is made, the material can stretch, change shape, and fold. Thus, the material can be tailored via chemistry for a variety of specific applications.
  • Unlike synthetic polymers, because Kumar’s material is made of proteins and a bio-linking chemical, it can biodegrade, just like plant and animal proteins do naturally.
  • In the lab, the team found that the material degrades within a few days in acidic solution. Now, they are investigating what happens if they bury this material in the ground, which is the fate of many post-consumer plastics.
  • They have demonstrated that the protein-based material can form a variety of plastic-like products, including coffee cup lids and thin transparent films. It could also be used to make fire-resistant roof tiles, or higher-end materials like, car doors, rocket cone tips, or heart valves.
  • The next steps for this technology are to continue testing their mechanical properties, like strength or flexibility, as well as toxicity.
Prof Challa Kumar, Professor Emeritus of Chemistry, “fed up” with the tremendous amount of toxic waste people continually pump into the environment, felt compelled to do something. As a chemist, doing something meant using his expertise to develop new, sustainable materials
Fed Up With Toxicity Prof Challa Kumar, Professor Emeritus of Chemistry, “fed up” with the tremendous amount of toxic waste people continually pump into the environment, felt compelled to do something. As a chemist, doing something meant using his expertise to develop new, sustainable materials University of Connecticut

The other development: Kumar’s second technology uses a similar principle, but instead of just proteins, uses proteins reinforced with natural fibres, specifically cotton.

  • Just like the plastic-like protein materials, Kumar expects composite materials made from proteins and natural fibres will biodegrade without producing toxic waste.
  • In the lab, the scientists created many objects with protein-fabric composites, which include small shoes, desks, flowers, and chairs. This material contains textile fibres which serve as the linking agent with the proteins, rather than the cross-linking chemical Kumar uses for the protein-based plastics.
  • The crosslinking provides the novel material with the strength to withstand the weight that would be put on something like a chair or a table. The natural affinity between fibres and proteins is why it’s so hard to get food stains out of clothing. This same attraction makes strong protein-fabric materials.
  • While the team has only worked with cotton so far, they expect other fibre materials, like hemp or jute, would behave similarly due to their inherent but common chemical properties with cotton.

What they said:

Everyone should think about replacing fossil fuel-based materials with natural materials anywhere they can to help our civilisation to survive. The house is on fire, we can’t wait. If the house is on fire and you start digging a well—that is not going to work. It’s time to start pouring water on the house. Chemistry is the only thing standing in our way. If we understand protein chemistry, we can make protein materials as strong as a diamond or as soft as a feather.

Challa Kumar
Professor Emeritus of Chemistry
University of Connecticut

 
 
  • Dated posted: 17 November 2023
  • Last modified: 1 January 2025